Msc Chemistry Programme Outcome

Msc chemistry programme

Programme Specific Outcomes

 PSO 1 : Develop a better understanding of the current chemical principles,
methods and theories with the ability to critically analyse at an advanced
level.
 PSO 2 : Acquire solid knowledge of classical and modern experimental
techniques and interpretation of results; thereby acquire the ability to plan and
carry out independent projects.
 PSO 3 : Develop the qualities of time management and organization, planning and executing experiments.
 PSO 4 : Have a good level of awareness of the problems associated with
health, safety and environment.
 PSO 5 : Understand how chemistry relates to the real world and be able to
communicate their understanding of chemical principles to a lay audience and
as well apply the knowledge when situation warrants.
 PSO 6 : Learn to search scientific literature and databases, extract and retrieve the required information and apply it in an appropriate manner.
 PSO 7 : Demonstrate proficiency in undertaking individual and/or team-based laboratory investigations using appropriate apparatus and safe laboratory practices.
 PSO 8 : Develop analytical solutions to a diversity of chemical problems
identified from application contexts; critically analyse and interpret qualitative
& quantitative chemical information’s.
 PSO 9 : Set the scene to make use of the wide range of career options open to chemistry graduates.

SEMESTER 1:

CH 211 INORGANIC CHEMISTRY I

Course outcome

 Employ crystal field theory in analysing the splitting of d orbitals in octahedral, tetragonal, square planar, tetrahedral, trigonal bipyramidal and square pyramidal fields, calculate crystal field stabilization energy and interpret octahedral site stabilization energy.
 Apply jahn-teller theorem and demonstrate evidence for jt effect, static and dynamic jt effect.
 Illustrate mot for octahedral and tetrahedral complexes with and without pi bonds and construct mo diagrams.
 Critically evaluate data from a variety of analytical chemistry techniques and apply knowledge of the statistical analysis of data.
 Apply tg, dta and dsc in the study of metal complexes.
 Explain the functioning of the frontier materials in inorganic chemistry like solid electrolytes, solid oxide fuel cells, rechargeable battery materials, molecular materials and fullerides.
 Explain the preparation, properties and structure of isopoly acids of mo, w and v and heteropoly acids of mo and w
 Explain preparation and properties of xenon fluorides, and noble gas compounds, aluminosilicates, zeolites and silicones and identify the importance of shape selectivity.
 Identify the chemical processes occurring naturally in earth’s atmospheric, aquatic and soil environments and evaluates the impacts of human perturbations to these processes.

SEMESTER 1:

CH 212  ORGANIC CHEMISTRY I
Course outcome

 Write down the iupac name of polycyclic, spirocyclic and heterocyclic compounds
and draw the structures from the iupac name of these compounds.
 Determine r and s, p and m, e and z configuration of compounds with chiral centres, biphenyls, allenes, spiranes and draw the configurations in dash and wedge formula, or zig –zag configurations.
 Detect prochirality in a compound and explain relevance of prochirality .
 Explain chiral centre, chiral axis and chiral plane with examples, stability of
conformations, stereoselective and stereospecific reactions.
 Calculate cotton effect of a compound from its structure and configuration.
 Explain different methods for generation of free radical and different types of free radical reactions- predict the products in a free radical reaction.
 Describe different types mechanism of substitution, elimination, hydrolysis and addition reactions.
 Differentiate the rate, mechanism and stereochemistry influenced by solvent, substrate structure, intermediate stability.
 Predict the products or reactants or reagents in selected types of reactions.
 Design the mechanism of selected reactions.
 Understand how chemistry relates to the real world and be able to communicate their understanding of chemical principles to a lay audience and as well apply the knowledge when situation warrants.
 Learn to search scientific literature and databases, extract and retrieve the required information and apply it in an appropriate manner.

SEMESTER 1: CH 213 PHYSICAL CHEMISTRY I
Course outcome

 Outline the development of quantum mechanics and its tools and apply them in determining the wave functions and energies of moving particles.
 Recognize the nature of adsorption and propose theories and choose theoretical and instrumental methods of measurements of surface property.
 Understand theory and mechanism of catalytic action.
 Correlate thermodynamic properties and apply them in systems.
 Understand theories, mechanism and, kinetics of reactions and solve numerical problems.
 Identify point groups and construct character table and predict hybridisation and spectral properties of molecules
 Develop analytical solutions to a diversity of chemical problems identified from application contexts; critically analyse and interpret qualitative & quantitative chemical informations.
 Learn theoretical as well as practical aspects of physical chemistry in various applications

SEMESTER 1:

CH 214 INORGANIC CHEMISTRY PRACTICALS I
Course outcome

 Interpret data from an experiment, including the construction of appropriate graphs and the evaluation of errors.
 Estimate volumetrically the concentration of zn, mg and ni using edta and the volumetric estimation of fe.
 Estimate volumetrically the hardness of water and concentration of ca in water samples using edta.
 Estimate colorimetrically the concentration of chromium – (using diphenyl
carbazide), iron (using thioglycollic acid), iron (using thiocyanate), manganese
(using potassium periodate), nickel (using dimethyl glyoxime).
 Carry out the preparation of the metal complexes potassium trioxalatochromate (iii), tetraammoniumcopper (ii) sulphate, hexamminecobalt (iii) chloride.
 Record the uv spectra, ir spectra, magnetic susceptibility, tg, dta and xrd of the complexes prepared.

SEMESTER 1:

CH 215 ORGANIC CHEMISTRY PRACTICALS I
Course outcome

 Interpret data from an experiment, including the construction of appropriate graphs and the evaluation of errors.
 Determine the correct method for separation of a binary mixture and make the separated compounds in pure form.
 Develop thin layer chromatogram of a compound and determine its purity.
 Separate two compounds by column chromatography.
 Differentiate the products by spectroscopic methods.
 Solve gc ms and lc ms of a compound to ascertain purity and identity, apply the basic principles
 To employ green chemical principles in the synthesis of organic compounds

SEMESTER 1:

CH 216 PHYSICAL CHEMISTRY PRACTICALS I
Course outcome

 Construct the freundlich and langmuir isotherms for adsorption of acetic/oxalic acid on active charcoal/ alumina and determine the concentration of acetic/ oxalic acid
 Determine the rate constant, arrhenius parameters, rate constant and concentration using kinetics
 Construct the ternary phase diagram of acetic acid chloroform-water system and out the procedure in an unfamiliar situation to find out the composition of given homogeneous mixture.
 Construct the tie-line in the ternary phase diagram of acetic acid chloroform-water system
 Determine distribution coefficient using distribution law.
 Determine the equilibrium constant employing the distribution law.
 Determine the coordination number of cu2+ in copper- ap 7, 8 [19] ammonia complex.
 Determine kf of solid solvent, molar mass of non-volatile solute, mass of solvent and composition of given solution
 Determine kt of salt hydrate, molar mass of solute, mass of salt hydrate and
composition of given solution.
 Determine surface tension and parachor of liquids.
 Determine the concentration of given strong acid/alkali.
 Determine the heat of ionisation of acetic acid.
 To construct the phase diagram and determine the composition of an unknown mixture
 To ascertain the relationship between surface tension with concentration of a liquid and use this to find out the composition of given homogeneous mixture.
 Determine the heat of displacement of cu2+ by zn.

SEMESTER 2:

CH 221 INORGANIC CHEMISTRY II
Course outcome

 Obtain the term symbols of dn system and determine the splitting of terms in weak and strong octahedral and tetrahedral fields
 Explain the correlation diagrams for dn and d10-n ions in octahedral and tetrahedral fields and interprets electronic spectra of complexes.
 Relates crystalline structure to x-ray diffraction data and the reciprocal lattice and explains the diffraction methods
 Explains crystal defects .
 Elaborates the structure of selected compounds of ax, ax2, amx2, abx3 and spinels.
 Explains the electronic structure of solids using free electron theory and band theory.
 Understands the differences in semiconductor and dielectric materials and their electrical and optical properties
 Explain the structure and reactions of s–n, p–n, b–n, s– p compounds and boron hydrides.
 Analyse the topological approach to boron hydride structure and estimates styx numbers and apply wade’s rules in borane and carboranes.
 Identify the electronic configurations and term symbols of lanthanides and actinides.
 Sketches the shapes of f orbital and shows their splitting in cubic ligand field.
 Apply magnetic measurements in the determination of structure of transition metal complexes.
 Elaborates the importance of the beach sands of kerala and their important
components.

SEMESTER 2:

CH222 ORGANIC CHEMISTRY II
Course outcome

 Discuss the fundamentals, operating principles and instrumentation of separation techniques.
 Differentiate the principle and applications of phase transfer catalysis with examples.
 Explain the hammet parameters of reaction and design an experiment to confirm the mechanism of a reaction.
 Understand that the outcomes of pericyclic reactions may be understood in terms of frontier orbital interactions, correlation diagram, mobius and huckel approach.
 Recall and define the various types of pericyclic reaction; define such terms as ‘conrotatory’, ‘suprafacial’.
 State the synthetic importance of the above cycloaddition and rearrangement reactions, and give disconnections of target compounds corresponding to these reactions.
 Describe the fate of excited molecule based on jabolonoski diagram, predict the course of an organic photochemical reaction and identify the product with the type of functional group.
 Describe the various methods of determining reaction mechanisms and basic thermodynamic principles of organic reactions.
 Identify different types of rearrangement reactions, determine the product of the reaction applying migratory aptitude, and reproduce the evidences for the mechanism of the reaction.
 Predict and rationalise the outcomes of pericyclic reactions including
stereospecificity, regioselectivity, and stereoselectivity.

SEMESTER 2 :CH 223 PHYSICAL CHEMISTRY II
Course outcome

 Apply quantum mechanical principles in solving both real and imaginary spherical harmonics systems-multi electron systems and analyse spectral lines.
 Predict likely spectral characteristics of given molecular species, and be able to rationalise those characteristics on the basis of structural and electronic arguments.
 Understand and apply of theories of heat capacity.
 Understand theories of electrolytes and electrochemical reactions.
 Ascertain the application of electrochemistry in industrial fields.
 Acquire skill in solving numerical problems.
 To understand the physical and chemical principles that underlie molecular structure determination techniques like microwave, vibrational, raman and electronic
spectroscopy.
 Acquire knowledge of basics of statistical mechanics and compare statistical
methods.
 Understand the theories and applications behind various types of analytical
techniques in electrochemistry

SEMESTER 3 :

CH 231 INORGANIC CHEMISTRY III
Course outcome

 Examine the bonding in simple and polynuclear carbonyls with and without bridging and complexes with linear π donor ligands.
 Explain the structure and bonding of ferrocene and dibenzene chromium with the help of mo theory.
 Contrasts the thermodynamic and kinetic stability of complexes, analyses the factors affecting stability of complexes and explains the methods of determining stability constants.
 Classifies ligand substitution reactions and explains its kinetics and various
mechanisms.
 Explain the principles of spectroscopic methods employed in inorganic chemistry and their applications in the study of metal complexes.
 Demonstrate a knowledge of fundamental aspects of the structure of the nucleus, radioactive decay, nuclear reactions, counting techniques.
 Evaluate the role of nuclear chemistry to find the most suitable measures,
administrative methods and industrial solutions to ensure sustainable use of the world’s nuclear resources.
 Demonstrate knowledge of advanced content in the areas of inorganic chemistry such as in organometallic compounds, bioinorganic compounds, spectroscopic methods in inorganic chemistry and nuclear chemistry.
 Understand fundamental reaction types and mechanisms in organometallics and to employ them to understand selected catalytic processes in industry.
 Analyze the chemical and physical properties of metal ions responsible for their biochemical action as well as the techniques frequently used in bioinorganic chemistry such as oxygen transport, e-transfer, communication, catalysis, transport, storage etc

SEMESTER 3 :

CH 232 ORGANIC CHEMISTRY III
Course outcome

 Describe and explain the physical and chemical principles that underlie molecular structure determination techniques such as uv-visible, ir, mass and nmr spectroscopy.
 Calculate λmax of a compound, apply ir frequency table to determine the functional groups present in the molecule, interpret mass spectrum of compound from fragmentation.
 Devise a 2 d nmr of a compound based on learned principles and solve the structure of a compound based on nmr data.
 Discuss organic transformations with organometallic compounds and predict the products of the reactions.
 Propose the retro synthetic pathways to a variety of molecules
 Propose mechanisms for chemical reactions, given starting materials, reagents, conditions, and/or products.
 Devise combinatorial method to create a library of compounds.
 Give examples of stereoselective, regioselective and chemoselective reductions and oxidations.
 Apply knowledge of molecular structure determination using uv-visible, ir, mass and nmr spectroscopic techniques to identify and/or characterise chemical compounds from experimental data.
 Compare the reactions and mechanism and determine the products of a selected set of reactions
 Predict likely spectral characteristics of given molecular species; solve the structures of unknown molecules using appropriate spectroscopic techniques

SEMESTER 3 :

CH 233 PHYSICAL CHEMISTRY III
Course outcome

 Compare molecular orbital theory and valence bond theory.
 Understand the properties of gases and liquids and the nature of the intermolecular forces in them.
 Describe the principle behind the determination of surface tension and coefficient of viscosity.
 Understand the quantum mechanical and non-quantum mechanical methods in computational chemistry, potential energy surface and basis functions.
 Write the z matrix of simple molecules.
 Acquire skill in solving numerical problems
 Understand the theories of chemical bonding and their application with help of approximate methods predict the nature of orbitals and molecular spectra.
 Describe and explain the physical and chemical principles that underlie molecular structure determination techniques like nmr, esr, mossbauer, nqr and pes spectroscopy.
 Judge the degrees of freedom of systems and understand theories of irreversible thermodynamic systems.

SEMESTER 3 :

CH 234 INORGANIC CHEMISTRY PRACTICALS – II
Course outcome

 Interpret data from an experiment, including the construction of appropriate graphs and the evaluation of errors.
 Perform cod, bod, do, tds analysis.
 Analyse the xrd of simple substances.
 Interpret tg and dta curves.
 Predict likely spectral characteristics of given metal complexes solve the structures of unknown metal complexes using appropriate spectroscopic techniques and magnetic measurements.
 Estimate a simple mixture of ions (involving quantitative separation) by volumetric and gravimetric methods.
 To perform water analysis using different parameters

SEMESTER 3 :CH 235 ORGANIC CHEMISTRY PRACTICALS – II
Course outcome

 Interpret data from an experiment, including the construction of appropriate graphs and the evaluation of errors.
 Develop paper chromatogram of a compound and determine its purity
 Estimate quantitatively the aniline, phenol, glucose, ascorbic acid and aspirin in a sample
 Analyse calorimetrically paracetamol, protein and ascorbic acid
 Predict likely spectral characteristics of given molecular species; solve the structures of unknown molecules using appropriate spectroscopic techniques
 To estimate organic compounds using both qualitative and quantitative methods
 Use green chemical principles in the synthesis

SEMESTER 3 : CH 236 PHYSICAL CHEMISTRY PRACTICALS – II
Course outcome

 Verify onsager equation and kohlraush’s law conductometrically .
 Determine the viscosity of liquid mixtures and use this in determining the
concentration of a component in a mixture.
 Interpret data from an experiment, including the construction of appropriate graphs and the evaluation of errors.
 Determine the strength of strong/ weak acids by conductometric titrations.
 Determine the activity and activity coefficient of electrolyte.
 Determine the concentration of a solution potentiometrically or ph metrically.
 Employ spectrophotometry in determining unknown concentration.
 Determine the concentration of a liquid mixture using a refractometer .
 Determine the unknown concentration of a given glucose solution.

SEMESTER 4:

CH 241 CHEMISTRY OF ADVANCED MATERIALS
Course outcome

 Understand and apply characterization tools for analysing nano structures.
 Outline and recognize the types of polymerization, kinetics and mechanisms.
 Discuss the synthesis and applications of selected classes of speciality polymers.
 Distinguish the types and important applications of smart materials.
 Understand the stereochemical aspects and methods for the determination of molecular weights of polymers
 Understand dimensions, synthesis, physicochemical properties of nanomaterials and its applications.

SEMESTER 4:

CH 242 (B) ORGANIC CHEMISTRY IV
Course outcome

 Define secondary metabolites from plants and animals
 Explain the biosynthesis of terpenes and sterols, illustrate the structural elucidation and synthesis of natural products.
 List the forces involved in molecular recognition and recognize molecular receptors.
 Discuss the methods of creating combinatorial libraries and its processing to locate lead molecule.
 Construct a solid phase synthesis of tripeptide from any three aminoacids, explain protection, deprotection and automated synthesis of peptides and nucleotides.
 Describe twelve principles green chemistry.
 Quote molecular recognition events in biological systems.
 Explain the various stages in drug development process, and outline the synthesis of drugs such as paracetamol, phenobarbital, diazepam etc
 Illustrate reactions in which green chemistry principles are applied and calculate atom economy.

SEMESTER 4:

CH 243 (A) DISSERTATION
Course outcomes

 Present information, articulate arguments and conclusions, in a variety of modes, to audiences in their field of research
 Develop an understanding of the requirements to undertake independent research in a chemistry field.
 Demonstrate an understanding of the relationship between scientific research and the progress of new knowledge in a global scenario.
 As part of a team or individually, design, conduct, analyse and interpret results of an experiment, and effectively communicate these in written reports and other formats
 Demonstrate an advanced theoretical and technical knowledge of chemistry as a creative endeavour; analyse, interpret and critically evaluate scientific information.

SEMESTER 4:CH 243 (B) VISIT TO R & D CENTRE
Course outcomes

 Understand the relevance of independent supervised research in a chemistry field and the need of well-developed judgement, adaptability and accountability as a practitioner or learner